Synthesis and catalytic evaluation of ruthenium(II) benzhydrazone complex in transfer hydrogenation of ketones
| Autor: | Thimma Sambamoorthy Manikandan, Sundar Saranya, Rengan Ramesh |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
010405 organic chemistry
Ligand Organic Chemistry Inorganic chemistry chemistry.chemical_element Noyori asymmetric hydrogenation Crystal structure 010402 general chemistry Transfer hydrogenation 01 natural sciences Biochemistry 0104 chemical sciences Ruthenium Catalysis Solvent chemistry Drug Discovery Polymer chemistry Single crystal |
| Zdroj: | Tetrahedron Letters. 57:3764-3769 |
| ISSN: | 0040-4039 |
| DOI: | 10.1016/j.tetlet.2016.07.020 |
| Popis: | Synthesis of new air stable octahedral ruthenium(II) carbonyl complex bearing O, and N-bidentate benzhydrazone ligand is reported. It has been characterized by elemental analysis, spectral methods and single crystal X-ray diffraction method. The new catalyst has been effectively applied to the transfer hydrogenation reaction of various ketones using isopropanol as a solvent and KOH as a base at 82 °C and the maximum conversion is achieved up to 100%. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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