Preparation of sulfur-containing conjugated microporous polymer for adsorbing iodine and Fe3+ sensing
| Autor: | Guangjuan Xu, Wei Xie, Shuran Zhang, Jiazhang Xu, Chan Yao, Yanhong Xu |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Aqueous solution Process Chemistry and Technology Inorganic chemistry Heteroatom Polymer Pollution Conjugated microporous polymer chemistry.chemical_compound Adsorption chemistry Polymerization Thiophene Chemical Engineering (miscellaneous) Waste Management and Disposal Lone pair |
| Zdroj: | Journal of Environmental Chemical Engineering. 9:106399 |
| ISSN: | 2213-3437 |
| DOI: | 10.1016/j.jece.2021.106399 |
| Popis: | The adsorption of iodine by porous organic polymers is an active research topic. Two new thiol-linked conjugated microporous polymers (SHCMPs) were successfully prepared by thioalkynes click polymerization. Lone pair electrons of heteroatoms can enhance the interaction between adsorbent and adsorbate, the ability of adsorbent to capture iodine can be improved by introducing electron-rich groups such as nitrogen, thiophene, fluorine, etc. The saturated iodine adsorption capacities of SHCMP-1 and SHCMP-2 are 590 and 495 wt.%, respectively. In addition, SHCMP-2 performs well in detecting Fe3+ in aqueous solution, which has potential importance for industrial application of water treatment. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect