Role of Coordination Number and Geometry in Controlling the Magnetic Anisotropy in Fe II , Co II , and Ni II Single‐Ion Magnets
Autor: | Arup Sarkar, Sourav Dey, Gopalan Rajaraman |
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Rok vydání: | 2020 |
Předmět: |
010405 organic chemistry
Chemistry Coordination number Organic Chemistry Ab initio Geometry General Chemistry Electronic structure Zero field splitting 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Ion Magnetization Magnetic anisotropy Ab initio quantum chemistry methods |
Zdroj: | Chemistry – A European Journal. 26:14036-14058 |
ISSN: | 1521-3765 0947-6539 |
Popis: | Since the last decade, the focus in the area of single-molecule magnets (SMMs) has been shifting constructively towards the development of single-ion magnets (SIMs) based on transition metals and lanthanides. Although ground-breaking results have been witnessed for DyIII -based SIMs, significant results have also been obtained for some mononuclear transition metal SIMs. Among others, studies based on CoII ion are very prominent as they often exhibit high magnetic anisotropy or zero-field splitting parameters and offer a large barrier height for magnetisation reversal. Although CoII possibly holds the record for having the largest number of zero-field SIMs known for any transition metal ion, controlling the magnetic anisotropy in these systems are is still a challenge. In addition to the modern spectroscopic techniques, theoretical studies, especially ab initio CASSCF/NEVPT2 approaches, have been used to uncover the electronic structure of various CoII SIMs. In this article, with some selected examples, the aim is to showcase how varying the coordination number from two to eight, and the geometry around the CoII centre alters the magnetic anisotropy. This offers some design principles for the experimentalists to target new generation SIMs based on the CoII ion. Additionally, some important FeII /FeIII and NiII complexes exhibiting large magnetic anisotropy and SIM properties are also discussed. |
Databáze: | OpenAIRE |
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