1-Methylbenzothiazolinospiro-2,3'-(2-methyl[3H]phenanthr[9,10-b][1,4]oxazine) and 1-Methylbenzothiazolinospiro-2,3'-(2'-methyl[3H]naphth[2,1-b][1,4]oxazine)

Autor:	X. Sun, E. T. Knobbe, Y. Liang, E. M. Holt, M. Fan
Rok vydání:	1997
Předmět:	Delocalized electron Photochromism Bicyclic molecule Stereochemistry Chemistry Polymer chemistry Electron delocalization Cationic polymerization Molecule General Medicine Crystal structure General Biochemistry Genetics and Molecular Biology
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 53:820-823
ISSN:	0108-2701
DOI:	10.1107/s0108270197000012
Popis:	The single-crystal X-ray structures of two thia­zolinospiro derivatives, C24H18N2OS and C20H16N2OS, suggest that their lack of photochromic behavior is due to electron-pair delocalization which reduces potential stabilization of a cationic intermediate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9f5a508069bba91ae75e2e1be66277c6 https://doi.org/10.1107/s0108270197000012 Zobrazit plný text záznamu Plný text