Oxygen-manganese porphyrinate-sodium borohydride system for oxidizing aromatic hydrocarbons

Autor:	L. L. Vasil'eva, K. K. Pivnitskii, E. A. Lukashova, A. B. Solov'eva
Rok vydání:	1990
Předmět:	Reducing agent Inorganic chemistry chemistry.chemical_element General Chemistry Manganese Porphyrin Oxygen chemistry.chemical_compound Sodium borohydride chemistry Oxidizing agent polycyclic compounds Organic chemistry Molecular oxygen Tetralin
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:1243-1249
ISSN:	1573-9171 0568-5230
Popis:	In the presence of sodium borohydride as reducing agent, porphyrin complexes of manganese catalyze the oxidation of 2,6-dimethylnaphthalene by molecular oxygen, resulting in a mixture of polyoxidized tetralin derivatives, among which products containing 1,3-diol, epoxyalcoholic, and β-hydroxyketonic groupings predominate. The nature of the components of the oxidizing system has a substantial influence on the ratio of products and the rate of oxidation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9f516bd728f786be8b3561f2fc8620ba https://doi.org/10.1007/bf00962391 Zobrazit plný text záznamu Full text from SpringerLink