Tropylium salts as efficient organic Lewis acid catalysts for acetalization and transacetalization reactions in batch and flow

Autor:	Thanh Vinh Nguyen, Demelza J. M. Lyons, Dieter Enders, Reece D. Crocker
Rok vydání:	2017
Předmět:	chemistry.chemical_classification 010405 organic chemistry Chemistry Environmental Chemistry Organic chemistry Lewis acids and bases 010402 general chemistry 01 natural sciences Pollution Aldehyde 0104 chemical sciences Catalysis
Zdroj:	Green Chemistry. 19:3993-3996
ISSN:	1463-9270 1463-9262
DOI:	10.1039/c7gc01519d
Popis:	Acetalization reactions play significant roles in the synthetically important masking chemistry of carbonyl compounds. Herein we demonstrate for the first time that tropylium salts can act as organic Lewis acid catalysts to facilitate acetalization and transacetalization reactions of a wide range of aldehyde substrates. This metal-free method works efficiently in both batch and flow conditions, prompting further future applications of tropylium organocatalysts in green synthesis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9f506775dfdf9973f390bb3ff2eab672 https://doi.org/10.1039/c7gc01519d Zobrazit plný text záznamu