Nitrosobenzene as a two-electron ligand in ?-cyclopentadienyl and carbonyl complexes with group VI and VII transition metals

Autor:	V. F. Sizoi, D. V. Zagorevskii, D. N. Kursanov, S. P. Dolgova, V. N. Setkina
Rok vydání:	1982
Předmět:	Chemistry Ligand chemistry.chemical_element Metal carbonyl General Chemistry Rhenium Photochemistry Medicinal chemistry Nitrosobenzene chemistry.chemical_compound Aniline Cyclopentadienyl complex Transition metal Mass spectrum
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 31:1239-1243
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00955988
Popis:	1. Previously unknown derivatives of cymantrene and its rhenium analog [(η5-C5H5)M(CO)2(PhNO)] (M = Mn, Re) with nitrosobenzene as two-electron ligand, and also nitrosobenzene derivatives of group VI B metal carbonyl, were obtained and characterized. 2. All the compounds with PhNO ligands contain phenylnitrene and aniline ions in the mass spectra, the intensity of the latter being maximal. 3. In [W(CO)5(PhNO)], nitrosobenzene is extraordinarily easily reduced to the aniline ligand.
Databáze:	OpenAIRE
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