Size Effect In The Inhibition of the Liquid-Phase Oxidation of Benzyl Alcohol by Iron(III) Oxide-Hydroxide Nanoparticles

Autor:	Ye. Yu. Kalishyn, Peter E. Strizhak, T. M. Kameneva, I. B. Bychko, E. V. Polunkin
Rok vydání:	2014
Předmět:	chemistry.chemical_compound chemistry Atmospheric oxygen Benzyl alcohol Radical Inorganic chemistry Liquid phase Nanoparticle General Chemistry Chain termination Peroxide Iron(III) oxide-hydroxide
Zdroj:	Theoretical and Experimental Chemistry. 50:304-310
ISSN:	1573-935X 0040-5760
DOI:	10.1007/s11237-014-9380-8
Popis:	This is the first report of the inhibitory effect of iron(III) oxide-hydroxide nanoparticles on the liquid-phase radical-chain oxidation of benzyl alcohol by atmospheric oxygen. The dependence of the rate of oxidation of benzyl alcohol by atmospheric oxygen on the nanoparticle diameter in the range 1-30 nm is given by a curve with a maximum for nanoparticles with diameter ~9 nm. The inhibition of the oxidation of benzyl alcohol is attributed to an increase in the rate of chain termination reactions due to the reaction of the nanoparticles with peroxide radicals.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9f447539e55511576e9ee540d3052bab https://doi.org/10.1007/s11237-014-9380-8 Zobrazit plný text záznamu Plný text ve formátu PDF