Synthesis of a novel CO2-based alcohol amine compound and its usage in obtaining a water- and solvent-resistant coating
| Autor: | Feng Wang, Xiaoyun Li, Maoqing Kang, Yuhua Zhao, Qifeng Li, Junwei Wang, Jiexi Ke |
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| Rok vydání: | 2018 |
| Předmět: |
Diglycidyl ether
Materials science General Chemical Engineering Alcohol 02 engineering and technology General Chemistry engineering.material 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Solvent chemistry.chemical_compound Coating chemistry Diamine Polymer chemistry engineering Molecule Amine gas treating 0210 nano-technology Polyurethane |
| Zdroj: | RSC Advances. 8:8615-8623 |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/c7ra12180f |
| Popis: | A five-membered cyclo-carbonate, prepared by cycloaddition reaction from CO2 and 1,4-butanediol diglycidyl ether, was reacted with excessive diamine and formed a urethane group-containing new product. Structural characterization was performed for the new alcohol amine, which can be applied to the manufacture of polyurethane coatings as a chain extender. The new chain extender-based polyurethane coatings exhibited excellent water, salt, and solvent resistance and promising mechanical strength. Importantly, the unique performance of the prepared polyurethane coatings should be ascribed to the introduction of a hydroxyl group in the polyurethane molecule. The strengthened hydrogen bonding enlarged the cohesion of the polyurethane coatings and prohibited the solvents from permeating. |
| Databáze: | OpenAIRE |
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