Kinetics of Pu(IV) reduction with zinc amalgam in sulfuric acid solutions

Autor:	V. N. Momotov, E. A. Erin, V. M. Chistyakov
Rok vydání:	2015
Předmět:	medicine.diagnostic_test Activated complex Inorganic chemistry Kinetics Enthalpy Kinetic scheme Sulfuric acid Rate equation Gibbs free energy chemistry.chemical_compound symbols.namesake chemistry Spectrophotometry medicine symbols Physical and Theoretical Chemistry Nuclear chemistry
Zdroj:	Radiochemistry. 57:403-408
ISSN:	1608-3288 1066-3622
DOI:	10.1134/s1066362215040116
Popis:	The kinetics of Pu(IV) reduction with zinc amalgam under different conditions [H2SO4 concentration 0.5–4.0 M, initial Pu(IV) concentration (1.11–4.80) × 10−3 M, temperature 294.0–323.0 K] was studied by spectrophotometry. The kinetic scheme of the Pu(IV) transformation and the rate law were suggested, and the reduction rate constants were determined. The activation energies Ea and the thermodynamic functions of formation of the activated complex (activation Gibbs energy ΔG≠, enthalpy ΔH≠, entropy ΔS≠) were determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9f36399e833eedb0071c159602f268fb https://doi.org/10.1134/s1066362215040116 Zobrazit plný text záznamu Full text from SpringerLink