Brominative Deoxygenation of some aldehydes and ethers
Autor: | Ulrich von Roman, Jakob Ruhdorfer, Claudia Behringer, Rudolf Knorr |
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Rok vydání: | 1994 |
Předmět: | |
Zdroj: | Journal f�r Praktische Chemie/Chemiker-Zeitung. 336:260-262 |
ISSN: | 1521-3897 0941-1216 |
Popis: | Three aldehydes (4a–c) are transformed into 1,1-dibromides (6a–c) by 2,2,2-tribromo-2,2-dihydro-1,3,2-benzodioxaphosphole (2). This reagent (2) is also very active in the cleavage of ethers; its reactions may show some features of carbonium as well as of SN2 character. |
Databáze: | OpenAIRE |
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