Brominative Deoxygenation of some aldehydes and ethers

Autor: Ulrich von Roman, Jakob Ruhdorfer, Claudia Behringer, Rudolf Knorr
Rok vydání: 1994
Předmět:
Zdroj: Journal f�r Praktische Chemie/Chemiker-Zeitung. 336:260-262
ISSN: 1521-3897
0941-1216
Popis: Three aldehydes (4a–c) are transformed into 1,1-dibromides (6a–c) by 2,2,2-tribromo-2,2-dihydro-1,3,2-benzodioxaphosphole (2). This reagent (2) is also very active in the cleavage of ethers; its reactions may show some features of carbonium as well as of SN2 character.
Databáze: OpenAIRE