Hexadecanuclear Copper Monothiocarbonates: An Emissive Cluster Building Block

Autor:	Pilli V. V. N. Kishore, Arvind Kumar Gupta, Chen-Wei Liu, Yuan‐Jang Chen, Jian-Hong Liao
Rok vydání:	2017
Předmět:	Photoluminescence 010405 organic chemistry Chemistry Ligand Supramolecular chemistry chemistry.chemical_element 010402 general chemistry Photochemistry Block (periodic table) 01 natural sciences Copper 0104 chemical sciences Inorganic Chemistry Crystallography Cluster (physics) Luminescence
Zdroj:	European Journal of Inorganic Chemistry. 2017:1989-1993
ISSN:	1099-0682 1434-1948
DOI:	10.1002/ejic.201700070
Popis:	A novel CuI cluster, Cu16L16·2CH3COCH3 (1), derived from a cyclohexylmonothiocarbonate ligand (L) was synthesized and structurally characterized. Coordinated-solvent-replacement reactions of 1 with various N-donor ligands to provide 2–5 were demonstrated. Clusters 1–3 and 5 display photoluminescence, whereas 4 is nonemissive. It appears that the emission characteristic of 1 can be tuned by ancillary N-donor ligands.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9ed31d74f2f72a36cd8c3b40b5d1efc9 https://doi.org/10.1002/ejic.201700070 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.