Relationship between global indices of reactivity, electrodonating and electroaccepting powers, and the hammet constant in isatoic anhydride derivatives

Autor:	Myrna H. Matus, Fernando R. Ramos-Morales, L. Cruz-Kuri, José Correa-Basurto, J. S. Durand-Niconoff, Jesús Samuel Cruz-Sánchez
Rok vydání:	2011
Předmět:	Computational chemistry Isatoic anhydride Chemistry Reactivity (chemistry) General Chemistry Constant (mathematics) Gas phase
Zdroj:	Journal of Chemical Sciences. 123:719-725
ISSN:	0973-7103 0974-3626
DOI:	10.1007/s12039-011-0119-y
Popis:	The possible correlation between Hammett’s constant (σp), a characteristic parameter of functional groups with electrodonating or electroaccepting properties, and two indices of global reactivity were calculated in the gas phase. Parameters associated to a set of 22 structural variants of isatoic anhydride (2H–3, 1–benzoxazin–2,4(1H)–dione, ISA), replaced with diverse functional groups, were explored applying linear and quadratic statistical models for numerical analysis of the results.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9ecc65f81293cc791c7b720db2bf0645 https://doi.org/10.1007/s12039-011-0119-y Zobrazit plný text záznamu Plný text ve formátu PDF