Stereoselectivity in the formation of tricarbonyliron complexes of some dihydrobiphenyls

Autor:	B. M. Ratnayake Bandara, Brian Chauncy, Arthur J. Birch
Rok vydání:	1993
Předmět:	Allylic rearrangement Stereochemistry Organic Chemistry Substituent Biochemistry Inorganic Chemistry Metal chemistry.chemical_compound chemistry visual_art Materials Chemistry visual_art.visual_art_medium Stereoselectivity Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 444:137-141
ISSN:	0022-328X
DOI:	10.1016/0022-328x(93)83066-5
Popis:	Ratios of isomeric products in complexation of some substituted cyclohexa-1,4- and 1,3-dienes, using Fe(CO) 5 or Fe 3 (CO) 12 are significantly affected by the nature of an allylic substituent: CO 2 Me tends to direct the metal to its occupied face, Ph less so and Me is inhibitory. An appropriately substituted cyclohexadiene gives a single stereoisomer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9ec4a3eaf152f16b1dc505ad643e2524 https://doi.org/10.1016/0022-328x(93)83066-5 Zobrazit plný text záznamu