Interaction of ferrocene with styrene and methyl methacrylates in the media of different polarity
| Autor: | S. I. Kuznetsov, Yu. I. Puzin, Alexander A. Golovanov |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Chemistry Electron donor General Chemistry Electron acceptor 010402 general chemistry Photochemistry Methacrylate 01 natural sciences 0104 chemical sciences Styrene chemistry.chemical_compound Ultraviolet visible spectroscopy Monomer Ferrocene Polymer chemistry Methyl methacrylate |
| Zdroj: | Russian Journal of General Chemistry. 87:1026-1030 |
| ISSN: | 1608-3350 1070-3632 |
| DOI: | 10.1134/s107036321705022x |
| Popis: | The interaction of ferrocene with styrene and methyl methacrylate in media of different polarity (hexane, tetrachloromethane, and ethanol) has been studied by means of UV spectroscopy using the isomolar series method. For both monomers, intermediate complexes are formed, the medium polarity significantly affecting the complexes formation. Ferrocene acts differently in the interaction with styrene (being the electron acceptor) and methyl methacrylate (being the electron donor). It has been discovered that only in the case of ethanol a charge-transfer complex between ferrocene and styrene is formed. Possible structures of the intermediate complexes have been suggested. |
| Databáze: | OpenAIRE |
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