Visible-light-mediated semi-heterogeneous black TiO2/nickel dual catalytic C (sp2)–P bond formation toward aryl phosphonates

Autor:	Mona Hosseini-Sarvari, Mehdi Koohgard, Haniehsadat Karimitabar
Rok vydání:	2020
Předmět:	010405 organic chemistry Aryl chemistry.chemical_element Bond formation 010402 general chemistry Photochemistry 01 natural sciences 0104 chemical sciences Catalysis Dual (category theory) Inorganic Chemistry Nickel chemistry.chemical_compound chemistry Homogeneous Reusability Visible spectrum
Zdroj:	Dalton Transactions. 49:17147-17151
ISSN:	1477-9234 1477-9226
DOI:	10.1039/d0dt03507f
Popis:	The combination of black TiO2 nanoparticles (NPs) with a nickel catalyst provides a low-cost, sustainable, and reusable alternative dual catalytic system to a homogeneous counterpart (noble metals). This black TiO2-photoredox/nickel dual catalytic system has efficiently driven C–P bond formation between aryl iodides and diarylphosphine oxides under visible light, providing good to excellent yields as well as tolerating a variety of functional groups. The practical application of this semi-heterogeneous protocol has been highlighted by a sunlight experiment, a gram-scale reaction, and a reusability test.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9e6c2f3f4cf2bcd09db744f5694d065f https://doi.org/10.1039/d0dt03507f Zobrazit plný text záznamu