Synthesis, structure and reactivity of the homoleptic iron(II) complex of the novel 4′-(4‴-pyridyl-N-oxide)-2,2′:6′,2″-terpyridine ligand

Autor:	Andreas F. Thünemann, Jesús Pitarch López, Günter Reck, Dirk G. Kurth, Werner Kraus
Rok vydání:	2005
Předmět:	Chemistry Ligand Inorganic chemistry Oxide Pyridine-N-oxide Crystal structure Inorganic Chemistry chemistry.chemical_compound Crystallography Pyridine Materials Chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Terpyridine Homoleptic
Zdroj:	Inorganica Chimica Acta. 358:3384-3390
ISSN:	0020-1693
DOI:	10.1016/j.ica.2005.04.034
Popis:	The new ligand 4′-(4‴-pyridyl-N-oxide)-2,2′:6′,2″-terpyridine (pyNoxterpy) and its homoleptic iron(II) complex have been synthesised, and structural and spectroscopic studies have been carried out. The obtained results have been compared with the reported data for the parent ligand 4′-(4‴-pyridyl)-2,2′:6′,2″-terpyridine (pyterpy) and its homoleptic iron(II) complex. Significant differences between the spectral and electrochemical properties of the metal complexes have been found, derived from the changes in the electronic properties of the coordinated ligands.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9e53643f86f9f625307e99a196a948fd https://doi.org/10.1016/j.ica.2005.04.034 Zobrazit plný text záznamu Full Text from ScienceDirect