Modeling the Viscosity for (nC5+nC8), (nC5+nC10), (nC8+nC10) and (nC5+nC8+nC10) Systems with Peng-Robinson Viscosity Equation of State
Autor: | Shahin Khosharay, Khashayar Khosharay, Reza Karimi |
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Rok vydání: | 2016 |
Předmět: |
Equation of state
Chemistry General Chemical Engineering Thermodynamics Binary number 02 engineering and technology 021001 nanoscience & nanotechnology Viscosity 020401 chemical engineering 0204 chemical engineering Viscosity solution 0210 nano-technology Ternary operation Constant (mathematics) Mixing (physics) Bar (unit) |
Zdroj: | Periodica Polytechnica Chemical Engineering. 60:259-265 |
ISSN: | 1587-3765 0324-5853 |
DOI: | 10.3311/ppch.8632 |
Popis: | The aim of this modeling study is to improve the performance of the Peng-Robinson viscosity equation of state. To achieve this aim, the couple of Peng-Robinson viscosity equation of state and the proposed mixing rules has been applied for modeling the viscosities of the binary and ternary systems containing (nC5+nC8), (nC5+nC10), (nC8+nC10) and (nC5+nC8+nC10) for temperatures and pressures ranged (297.75-373.35) K and (49.95-246.26) bar, respectively. First, the pressure temperature-dependent and constant expressions for the binary interaction coefficients of binary systems have been determined. Subsequently, these empirical correlations of binary interaction coefficients have been applied to predict the viscosities for ternary mixture of (nC5+nC8+nC10 ). For this ternary mixture, the results of model show acceptable accuracy (overall AAD~7.77 % and 8.02 for mixing rule 1 and 2, respectively). |
Databáze: | OpenAIRE |
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