Cleavage of the carbon-silicon bond in 1-alkynylsilanes by silver nitrate: Protection of a terminal triple bond in hydrogenation reactions with the trimethylsilyl group

Autor:	J. F. Arens, H. M. Schmidt
Rok vydání:	2010
Předmět:	Aqueous solution Silicon Trimethylsilyl Silylation chemistry.chemical_element General Chemistry Cleavage (embryo) Photochemistry Triple bond Silver nitrate chemistry.chemical_compound chemistry Polymer chemistry Carbon
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas. 86:1138-1142
ISSN:	0165-0513
DOI:	10.1002/recl.19670861013
Popis:	It is possible to reduce non-terminal triple bonds in poly-ynes selectively when the terminal triple bonds are previously protected silylation. Desilylation after the reduction can be easily effected with aqueous alcoholic silver nitrate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9e4a1b06dda5256d6074e5df441f8ec1 https://doi.org/10.1002/recl.19670861013 Zobrazit plný text záznamu