1-Hexene Polymerization on a Highly Active Titanium–Magnesium Catalyst

Autor:	L. G. Echevskaya, Vladimir A. Zakharov, Mikhail A. Matsko
Rok vydání:	2020
Předmět:	Ethylene 010405 organic chemistry Magnesium technology industry and agriculture chemistry.chemical_element macromolecular substances General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Computer Science Applications 1-Hexene chemistry.chemical_compound chemistry Polymerization Chemical engineering Modeling and Simulation Molecule Titanium
Zdroj:	Kinetics and Catalysis. 61:40-57
ISSN:	1608-3210 0023-1584
DOI:	10.1134/s002315842001005x
Popis:	The review summarizes the results obtained by the authors in a study of the polymerization of 1‑hexene on a supported titanium–magnesium catalyst. The effects of the composition of a complex titanium–magnesium catalytic system, the composition of a reaction medium, and the conditions of polymerization on the activity of the catalyst and the molecular weight, molecular-weight distribution, and isotacticity of the resulting polyhexene were considered. The main factors (the composition of a catalytic system and the polymerization conditions) that allow one to control the catalyst activity and the molecular structure of polyhexene over wide ranges were determined. Specific features of the polymerization of 1-hexene in comparison with the polymerization of ethylene and propylene on titanium–magnesium catalysts are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9e4747839d2292534323caaebae3a2b8 https://doi.org/10.1134/s002315842001005x Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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