A co-ligand firstly introduced to 9-fluorenone-2,7-dicarboxylate-based MOF: synthesis, structure and photoluminescent property

Autor:	Wen-Wen Dong, Bing-Hai Wang, Wei Xia, Min-Le Han, Dong-Sheng Li, Yi-Qiang Mu
Rok vydání:	2014
Předmět:	Photoluminescence Materials science 9-fluorenone Stereochemistry Coordination polymer Ligand Fluorescence Hydrothermal circulation Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Materials Chemistry Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry Communications. 46:259-262
ISSN:	1387-7003
Popis:	Through hydrothermal reactions, 4,4′-bipyridine (bpy) co-ligands firstly was introduce to CdII–H2FDC system (H2FDC = 9-fluorenone-2,7-dicarboxylic acid), generating a new coordination polymer {[Cd2(FDC)2(bpy)]∙H2O}n (1). Compound 1 has a pillar-layer 2-fold interpenetrating pcu network, based on the square-grid tetranuclear [Cd4(COO)8] units. Interestingly, 1 shows a blue-shifted photoemission, as well as enhanced fluorescence lifetime compared with the pure H2FDC ligand.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9e2476256ae9bd68e0d01d24e857d86d https://doi.org/10.1016/j.inoche.2014.06.016 Zobrazit plný text záznamu Full Text from ScienceDirect