ChemInform Abstract: Novel Oxidative Rearrangement Product of the First trans,cis,cis,cis-( 5.5.5.5)Fenestrane Derivative

Autor:	M. A. Delong, Paul A. Wender, F. C. Wireko
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Fenestrane chemistry Stereochemistry Protein subunit Cyclopentene Single bond General Medicine Oxidative phosphorylation Derivative (chemistry) Cis–trans isomerism
Zdroj:	ChemInform. 28
ISSN:	0931-7597
Popis:	The structure of rel-(4S,6R,9S,11S)-1-hydroxy-16-methyl-14-oxapentacyclo[7.4.3.04,15.011,15.06,16]hexadeca-7-ene, C16H22O2, (IV), has been determined. This study thus establishes compound (III), the precursor of (IV), as the first trans,cis,cis,cis[5.5.5.5]fenestrane. The geometry around the central quaternary C atom of (IV) shows relatively little distortion. The C=C bond in the cyclopentene subunit is slightly shorter [1.305 (4) A] than normal. Similarly, small departures from normal are seen in several C–C single bonds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9e152cc27dc85df7aaeaac63fa1c6361 https://doi.org/10.1002/chin.199746035 Zobrazit plný text záznamu Plný text