1,3-Elimination in ?-halogen- and ?-ammonium-1-boraadamantane ate-complexes

Autor:	Yu. N. Bubnov, K. L. Cherkasova, Mikhail E. Gurskii, T. V. Potapova
Rok vydání:	1988
Předmět:	chemistry.chemical_compound chemistry Pyridine Halogen Organic chemistry Ammonium General Chemistry Medicinal chemistry Tetrahydrofuran Cyclopropane
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 37:334-338
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00957439
Popis:	1. Complexes of 2-(2-halogenoidethyl)-1-boraadamantanes with tetrahydrofuran and pyridine have been synthesized by the hydroboration-isomerization of 3-methoxy-7-(3-halogenoidpropyl)-3-borabicyclo[3.3.1]non-6-enes. 2. 4-Chloro-, and 2-(2-halogenoidethyl)-, and 2-(2-trimethylammoniumethyl)-1-boraadamantane ate-complexes undergo self-induced 1,3-elimination, resulting in the formation of substituted 3-borabicyclo[3.3.1]nonanes containing a cyclopropane fragment.
Databáze:	OpenAIRE
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