Selective synthesis of triacetin from glycerol catalyzed by HZSM-5/MCM-41 micro/mesoporous molecular sieve
| Autor: | Jiangyong Liu, Dan Wang, Yunlin Sun, Panming Jian, Ruiqi Jian, Zihao Wang |
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| Rok vydání: | 2019 |
| Předmět: |
Environmental Engineering
General Chemical Engineering 02 engineering and technology General Chemistry Microporous material 021001 nanoscience & nanotechnology Molecular sieve Biochemistry Catalysis chemistry.chemical_compound Acetic acid 020401 chemical engineering chemistry Chemical engineering MCM-41 Glycerol 0204 chemical engineering 0210 nano-technology Mesoporous material Triacetin |
| Zdroj: | Chinese Journal of Chemical Engineering. 27:1073-1078 |
| ISSN: | 1004-9541 |
| DOI: | 10.1016/j.cjche.2018.09.013 |
| Popis: | HZSM-5/MCM-41 molecular sieve (H-ZM) catalysts with well-defined micro/mesoporous structures were synthesized and showed high performance for selective synthesis of triacetin via the esterification reaction of glycerol with acetic acid. The conversion of glycerol was demonstrated to be 100% and the triacetin selectivity was over 91%, which can be attributed to the synergistic effect regarding suitable acidic property, excellent diffusion efficiency and good stability derived from the combined advantages of microporous molecular sieve HZSM-5 and mesoporous molecular sieve MCM-41. |
| Databáze: | OpenAIRE |
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