Substoichiometric determination of iridium using PAN as a reagent
Autor: | K. Ashok Rao, B. Rangamannar |
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Rok vydání: | 1985 |
Předmět: |
Health
Toxicology and Mutagenesis Metal ions in aqueous solution Public Health Environmental and Occupational Health chemistry.chemical_element Pollution Analytical Chemistry Metal Nuclear Energy and Engineering chemistry Liquid–liquid extraction visual_art Reagent Boiling visual_art.visual_art_medium Radiology Nuclear Medicine and imaging Chelation Iridium Spectroscopy Nuclear chemistry |
Zdroj: | Journal of Radioanalytical and Nuclear Chemistry Letters. 93:287-293 |
ISSN: | 1588-2780 0236-5731 |
DOI: | 10.1007/bf02165014 |
Popis: | Conditions are established for the substoichiometric determination of iridium employing 1-/2-pyridylyzo/-2-naphthol /PAN/ as a chelating agent. Iridium forms a red coloured complex /1∶2/ with PAN at pH 5 /acetate buffer/, on heating for 60 min in a boiling water bath. The complex was extracted with chloform. Tens of micrograms of iridium were determined with an accuracy of ±0.38%. Effects of diverse metal ions on the determination of iridium were studied and methods for suppression of interferences were developed. |
Databáze: | OpenAIRE |
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