Membrane transport of metal ions with lipophilic aminomethylphosphine oxides

Autor:	N. V. Kurnosova, S. V. Zakharov, R. R. Davletshin, Airat R. Garifzyanov, R. R. Galeev, R. A. Cherkasov
Rok vydání:	2011
Předmět:	Samarium Alkaline earth metal Membrane Chemistry Metal ions in aqueous solution Inorganic chemistry chemistry.chemical_element General Chemistry Scandium Membrane transport Alkali metal Selectivity
Zdroj:	Russian Journal of General Chemistry. 81:1464-1469
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363211070103
Popis:	The processes of membrane transport of ions of scandium(III), samarium(III), gadolinium(III), neodymium(III), aluminum(III), and a number of alkali and alkaline earth metals through liquid membrane impregnated with aminophosphoryl carriers of different structures were studied. Selectivity of bis (dialkylphosphinyl)amines towards scandium was found to be significantly higher than the selectivity of diphosphinylpiperazine and monophosphinylamine in particular. The dependence of transfer efficiency on the concentration of substrates and carriers was revealed. Optimal conditions for transporting rare and trace metal ions through the membrane were found, and the mechanism of transmembrane transport was discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9deccb50628d471bd812e680c09bd5e4 https://doi.org/10.1134/s1070363211070103 Zobrazit plný text záznamu Plný text ve formátu PDF