Spectroelectrochemical investigation of Azotobacter vinelandii bacterial ferritin

Autor: Liang-Shu Xu, He-Qing Huang, Jing-Wei Huang, Qing-Mei Lin, Feng-Zhang Zhang, Ding Zeng
Rok vydání: 1998
Předmět:
Zdroj: Bioelectrochemistry and Bioenergetics. 44:301-307
ISSN: 0302-4598
DOI: 10.1016/s0302-4598(97)00098-6
Popis: Bacterial ferritin of Azotobacter vinelandii (AvBF) contains a function in accepting electrons from platinum electrode directly for complete iron release in the absence of a mediator. The reduction potentials of electron tunnels of −125, −310, and −370 mV for iron release are determined by direct spectroelectrochemical technique, which suggests which should be defined as midpoint potentials of electron–tunnel–heme on the surface of protein shell. A kinetic study for complete iron release by the electrode reduction at −600 mV fits the zero-order reaction law.
Databáze: OpenAIRE