Hydrogen Bonding versus van der Waals Repulsion in 1,3,5-Trideoxy-1,3,5-tris(trimethylammonio)-cis-inositol Triiodide Sesquihydrate, C15H36N3O33+.3I−.1.5H2O
| Autor: | K. Hegetschweiler, H. W. Schmalle |
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| Rok vydání: | 1996 |
| Předmět: |
inorganic chemicals
Cyclohexane Hydrogen bond Stereochemistry education Cyclohexane conformation Intermolecular force General Medicine behavioral disciplines and activities humanities General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound Crystallography symbols.namesake chemistry Intramolecular force symbols Molecule Triiodide van der Waals force health care economics and organizations |
| Zdroj: | Acta Crystallographica Section C Crystal Structure Communications. 52:1288-1293 |
| ISSN: | 0108-2701 |
| DOI: | 10.1107/s0108270195013497 |
| Popis: | The crystal structure of the trimethylammonio-cis-inositol molecule displays one bifurcated intramolecular hydrogen bond of the form O-H...O, a strong intermolecular O-H...OW contact and possible intermolecular C-H...O and O-H...I interactions. C-H...I interactions may also be considered. As a result of the three bulky N(CH 3 ) 3 groups and the OH groups, increased puckering of the cyclohexane ring is observed compared with an undistorted ideal cyclohexane chair conformation. |
| Databáze: | OpenAIRE |
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