A new approach to visualizing the carbon black/natural rubber interaction layer in carbon black-filled natural rubber vulcanizates and to elucidating the dependence of mechanical properties on quantitative parameters
| Autor: | Yota Kokubo, Yuko Ikeda, Ryota Tsushi, Nobuo Kojima, Atsushi Kato |
|---|---|
| Rok vydání: | 2013 |
| Předmět: |
Materials science
Polymers and Plastics Composite number Carbon black Viscoelasticity Colloid and Surface Chemistry Natural rubber Phase (matter) visual_art Volume fraction Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Composite material Reinforcement Mixing (physics) |
| Zdroj: | Colloid and Polymer Science. 291:2101-2110 |
| ISSN: | 1435-1536 0303-402X |
| DOI: | 10.1007/s00396-013-2948-3 |
| Popis: | The viscoelastic behavior of carbon black (CB)-filled natural rubber (NR) vulcanizates is explained for the first time by applying a two-phase mixing law, excluding the CB phase, to the volume fraction of the CB/NR interaction layer (CNIL). For CB loadings of 20 phr or less, the CNIL of local CB aggregates induces the reinforcement effect of a series mechanical model of the mixing law. In contrast, for CB loadings of 30 phr or more, the CNIL that forms the CB network (CBN) generates the reinforcement effect of a parallel mechanical model of the mixing law. Therefore, the model of the mixing law presumably changes from a series mechanical model before CBN formation to a parallel one after the network forms. Additionally, employing this fraction, a transition caused by CBN formation was investigated. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink