Aldehydes from 4,4-Dimethyl-2-Oxazoline and Grignard Reagents:o-Anisaldehyde

Autor:	Albert I. Meyers, E. W. Collington, R. S. Brinkmeyer
Rok vydání:	2003
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Oxazolidine Hydrolysis chemistry Bromide Reagent Iodide Organic chemistry Oxazoline Tetrahydrofuran Methyl iodide
Zdroj:	Organic Syntheses
DOI:	10.1002/0471264180.os054.08
Popis:	Aldehydes from 4,4-dimethyl-2-oxazoline and grignard reagents: o-anisaldehyde intermediate: oxazolidine product: o-anisaldehyde reactant: 4,4-dimethyl-2-oxazoline reactant: N,4,4-Trimethyl-2-oxazolinium iodide byproduct: 5–10% o-bromoanisole product: C6H5CHO product: C6H5CH2CHO product: C6H5CHCHCHO product: C6H5CCCHO product: 2-CH3OC6H4CDO Keywords: Grignard and related reactions; hydrolysis, miscellaneous; 4,4-dimethyl-2-oxazoline, preparation of; hexamethylphosphoric triamide (HMPA); 2-methoxyphenylmagnesium bromide, preparation of; tetrahydrofuran; hexamethylphosphoric triamide (HMPA), toxicity; methyl iodide
Databáze:	OpenAIRE
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