Stereochemistry of nucleophilic attack on π-allylpalladium complexes. Evidence for cis-migration of acetate from palladium to carbon

Autor:	Eva E. Björkman, Christina Moberg, Ruth E. Nordberg, Jan-E. Bäckvall
Rok vydání:	1980
Předmět:	Metal chemistry Nucleophile Ligand visual_art visual_art.visual_art_medium Molecular Medicine Organic chemistry chemistry.chemical_element Medicinal chemistry Carbon Palladium
Zdroj:	J. Chem. Soc., Chem. Commun.. :943-944
ISSN:	0022-4936
DOI:	10.1039/c39800000943
Popis:	Formation of 4-methoxycyclohex-2-enyl acetate (3) from the π-allylpalladium complex (2) shows that the acetate has attacked the π-allyl ligand from the same side as the metal (cis-addition).
Databáze:	OpenAIRE
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