ChemInform Abstract: Nickel-Catalyzed Carboxylation of Benzylic C-N Bonds with CO2

Autor:	Ruben Martin, Morgane Gaydou, Toni Moragas
Rok vydání:	2016
Předmět:	Nickel Carboxylation Chemistry Electrophile chemistry.chemical_element General Medicine Reductive carboxylation Medicinal chemistry Catalysis
Zdroj:	ChemInform. 47
ISSN:	0931-7597
DOI:	10.1002/chin.201636049
Popis:	A user-friendly Ni-catalyzed reductive carboxylation of benzylic C-N bonds with CO2 is described. This procedure outperforms state-of-the-art techniques for the carboxylation of benzyl electrophiles by avoiding commonly observed parasitic pathways, such as homodimerization or β-hydride elimination, thus leading to new knowledge in cross-electrophile reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9d8218f175fe7f3d196a48e3b78b38d4 https://doi.org/10.1002/chin.201636049 Zobrazit plný text záznamu Plný text