Regeneration of Refinery Gas Treatment Superacid Catalysts by SCF Solvent Extraction

Autor: A. R. Davletshin, Yu. A. Khamzin, E. A. Ipatova, F. Sh. Vil’danov, E. G. Telyashev, M. N. Rakhimov, L. S. Doinitsyna, R. R. Shiriyazdanov, R. R. Abdyushev, V. R. Khakimov
Rok vydání: 2016
Předmět:
Zdroj: Chemistry and Technology of Fuels and Oils. 51:709-712
ISSN: 1573-8310
0009-3092
DOI: 10.1007/s10553-016-0661-x
Popis: The mechanisms of the process of extractive regeneration of oligomerization catalysts based on pillared clays in supercritical carbon dioxide (SCF-CO 3 ) in pure state and with addition of chlorine compounds (CCl 4 or C 2 H 4 Cl 2 ) are studied. The catalyst efficiency in the oligomerization process after regeneration with various SCF solvents is compared. The carburized and regenerated catalysts are studied by thermal analysis methods. Chlorine-containing additives are found to be effective in the regeneration process.
Databáze: OpenAIRE