Determination of ppb concentrations of transition metals by radioisotope-excited energy-dispersive X-ray spectrometry
| Autor: | J.L.S. Stewart, A. H. Pradzynski, R. E. Henry |
|---|---|
| Rok vydání: | 1976 |
| Předmět: |
inorganic chemicals
Health Toxicology and Mutagenesis Radiochemistry Public Health Environmental and Occupational Health Fluorescence spectrometry Analytical chemistry chemistry.chemical_element Vanadium Manganese Zinc Pollution Analytical Chemistry Mercury (element) Chromium Nuclear Energy and Engineering Transition metal chemistry Radiology Nuclear Medicine and imaging Spectroscopy Selenium |
| Zdroj: | Journal of Radioanalytical Chemistry. 32:219-228 |
| ISSN: | 1588-2780 0134-0719 |
| DOI: | 10.1007/bf02517754 |
| Popis: | Using ammonium pyrrolidine dithiocarbamate as precipitant and iron as a carrier, ppb concentrations of the following elements were coprecipitated from fresh water: vanadium, chromium, manganese, nickel, copper, zinc, selenium, mercury, and lead. Precipitates were collected on membrane filters then element concentrations were determined using energy dispersive X-ray fluorescence spectrometry. Calibration curves indicate sensitivities ranging from 0.4 ppb for V, Zn, As and Hg to 1.2 ppb for Pb. It is likely that this method of preconcentration can be directly incorporated into field sampling procedures, thus eliminating the problems of sample contamination or trace element losses by absorption on container walls. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink