The structural studies of the 4-nitrophenyl[bis(benzylthio)]methane by X-ray and spectroscopic methods. The possible outcome in its proton donor properties

Autor:	Małgorzata Ratajczak–Sitarz, Arnold Jarczewski, Andrzej Katrusiak, Iwona Binkowska
Rok vydání:	2009
Předmět:	Proton Organic Chemistry X-ray chemistry.chemical_element Crystal structure Photochemistry Medicinal chemistry Methane Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound chemistry X-ray crystallography Molecule Carbon Spectroscopy
Zdroj:	Journal of Molecular Structure. 928:54-58
ISSN:	0022-2860
DOI:	10.1016/j.molstruc.2009.03.013
Popis:	4-Nitrophenyl[bis(benzylthio)]methane was synthesized and used in structural study by X-ray diffraction combined with NMR and spectrophotometric method. In the crystal structure the molecule assumes the conformation where the acidic H-atom is difficult to access due to sterical hindrances of three surrounding phenyls. The acidic properties of 4-nitrophenyl[bis(benzylthio)]methane have been compared and discussed with the analogous disulfonyl carbon acid 4-nitrophenyl[bis(benzylsulfonyl)]methane.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9d5108e06f434fc3e4a830463cdc9638 https://doi.org/10.1016/j.molstruc.2009.03.013 Zobrazit plný text záznamu Full Text from ScienceDirect