Efficient visible light driven hydrogen generation using 9-(3,3-dimethyl-1,2-oxazetidine-N-yl)perylene-3,4-dicarboximide functionalized amino graphene
| Autor: | Sudha Kaliyaperumal, Abinaya Kalyanasundaram, Kalimuthu Palanisamy, Elangovan Arumugam, Sundharamurthi Subramani, Karthikaikumar Samuvelnesamani |
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| Rok vydání: | 2019 |
| Předmět: |
Hydrogen
Graphene Chemistry Process Chemistry and Technology chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Catalysis 0104 chemical sciences law.invention chemistry.chemical_compound law Covalent bond Photocatalysis Moiety 0210 nano-technology Imide Perylene General Environmental Science Hydrogen production |
| Zdroj: | Applied Catalysis B: Environmental. 242:293-301 |
| ISSN: | 0926-3373 |
| DOI: | 10.1016/j.apcatb.2018.09.098 |
| Popis: | Synthesis of oxazetidine substituted perylene dye N-(2,5-di-tert-butylphenyl)-9-(3,3-dimethyl-1,2-oxazetidine-N-yl)perylene-3,4-dicarboximide is reported. The imide moiety present in the reported dye was used to functionalize amino graphene. The 9-(3,3-dimethyl-1,2-oxazetidine-N-yl) perylene-3,4-dicarboximide was used as light harvester for photocatalytic hydrogen generation by covalently attaching on to amino graphene surface. The composite AG-DOPMI/Pt was prepared and found to be an efficient photocatalyts for hydrogen production from methanol:water mixture which can produce 1489 μmol/g hydrogen. The oxazetidine dye gives rise to the production of hydrogen generation even in the absence of sacrificial donor. |
| Databáze: | OpenAIRE |
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