Leonardo da Vinci’s drapery studies: characterization of lead white pigments by µ-XRD and 2D scanning XRF

Autor: Laurent Pichon, Bruno Mottin, Victor Gonzalez, Gilles Wallez, Thomas Calligaro
Rok vydání: 2015
Předmět:
Zdroj: Applied Physics A. 121:849-856
ISSN: 1432-0630
0947-8396
Popis: This work focuses on the composition and microstructure of the lead white pigment employed in a set of paintworks, using a combination of µ-XRD and 2D scanning XRF, directly applied on five drapery studies attributed to Leonardo da Vinci (1452–1519) and conserved in the Departement des Arts Graphiques, Musee du Louvre and in the Musee des Beaux-Arts de Rennes. Trace elements present in the composition as well as in the lead white highlights were imaged by 2D scanning XRF. Mineral phases were determined in a fully noninvasive way using a special µ-XRD diffractometer. Phase proportions were estimated by Rietveld refinement. The analytical results obtained will contribute to differentiate lead white qualities and to highlight the artist’s technique.
Databáze: OpenAIRE