Photocatalytic activity of layered niobates ANdNb2O7 (A = H, Li, Na, Rb, Cs)
| Autor: | Mikhail V. Chislov, Ivan A. Rodionov, Dmitry A. Porotnikov, Alena A. Burovikhina, Irina A. Zvereva |
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| Rok vydání: | 2016 |
| Předmět: |
Materials science
Aqueous solution Ion exchange 010405 organic chemistry Scanning electron microscope Intercalation (chemistry) Bioengineering Isopropyl alcohol Nanotechnology 010402 general chemistry Condensed Matter Physics 01 natural sciences 0104 chemical sciences chemistry.chemical_compound chemistry visual_art Materials Chemistry visual_art.visual_art_medium Photocatalysis Molecule Ceramic Electrical and Electronic Engineering Nuclear chemistry |
| Zdroj: | International Journal of Nanotechnology. 13:158 |
| ISSN: | 1741-8151 1475-7435 |
| DOI: | 10.1504/ijnt.2016.074531 |
| Popis: | Layered perovskite-type oxides ANdNb2O7 (A = Rb, Cs) were synthesised by the ceramic technique, ANdNb2O7 (A = Li, Na) - by ion exchange reaction in molten nitrates, and HNdNb2O7 - by ion exchange in an acid solution. These compounds were characterised by powder X-ray diffraction, TG analysis, UV-Vis diffuse reflection spectroscopy and scanning electron microscopy. Intercalation of water molecules into the interlayer space was detected only for NaNdNb2O7. Analysis of the photocatalytic activity was performed for photoinduced hydrogen evolution reaction from aqueous isopropyl alcohol. The highest photocatalytic activity was observed for RbNdNb2O7. |
| Databáze: | OpenAIRE |
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