Lineshape analysis of impurity Rydberg transitions in van der Waals solids: derivation of intermolecular potentials

Autor:	Franco Vigliotti, Majed Chergui
Rok vydání:	1998
Předmět:	Hydrogen Chemistry General Physics and Astronomy Semiclassical physics chemistry.chemical_element Spectral line symbols.namesake Reflection (mathematics) Impurity Rydberg formula symbols Physical and Theoretical Chemistry van der Waals force Absorption (chemistry) Atomic physics
Zdroj:	Chemical Physics Letters. 296:316-322
ISSN:	0009-2614
DOI:	10.1016/s0009-2614(98)01038-0
Popis:	Fluorescence depletion spectra of the A 2 Σ + (3 sσ ) Rydberg fluorescence of NO in rare-gas and hydrogen matrices are reported in the 0.9–1.3 eV region. Bands due to the Rydberg–Rydberg A 2 Σ + (3 sσ ) –C 2 Π (3 pπ ) and A 2 Σ + (3 sσ ) –D 2 Σ + (3 pσ ) transitions are observed. These spectral features are combined with ground-state absorption data of the A, C and D states and with A-state fluorescence data to generate a set of intermolecular potentials describing the impurity–matrix interaction in each state. The effective mode and harmonic approximations are made and the semiclassical reflection method is used.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9cf89637732d40e9a608a2a242fba7b2 https://doi.org/10.1016/s0009-2614(98)01038-0 Zobrazit plný text záznamu Full Text from ScienceDirect