Gelatin microsphere coated Fe3O4@graphene quantum dots nanoparticles as a novel magnetic sorbent for ultrasound-assisted dispersive magnetic solid-phase extraction of tricyclic antidepressants in biological samples
| Autor: | Siamak Javanbakht, Ali Reza Fakhari, Ahmad Shaabani, Zolfaghar Aladaghlo |
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| Rok vydání: | 2021 |
| Předmět: |
Sorbent
Materials science food.ingredient Ion-mobility spectrometry Graphene 010401 analytical chemistry Extraction (chemistry) Nanoparticle Nanochemistry 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences Gelatin 0104 chemical sciences Analytical Chemistry law.invention food law Solid phase extraction 0210 nano-technology Nuclear chemistry |
| Zdroj: | Microchimica Acta. 188 |
| ISSN: | 1436-5073 0026-3672 |
| DOI: | 10.1007/s00604-021-04727-y |
| Popis: | Gelatin microsphere-coated Fe3O4@graphene quantum dots (Fe3O4@GQD@GM) were designed and synthesized as a novel sorbent via ultrasonic-assisted dispersive magnetic solid-phase extraction (UA-DMSPE) method. The synthesized sorbent was identified and confirmed by FT-IR, XRD, VSM, and SEM techniques. UA-DMSPE was combined with corona discharge ion mobility spectrometry for trace determination of desipramine, sertraline, and citalopram. Effective parameters were considered and optimized. The proposed method, under optimal conditions, showed excellent linearity in different concentration ranges (2–700 ng mL–1, R2 > 0.995), repeatability (RSD < 5.1%), good sensitivity (LODs in the range 0.6–1.5 ng mL−1), high preconcentration factor (PF = 207–218), and acceptable relative recoveries (93.5–101.8%). Eventually, this method was used to determine tricyclic antidepressants in various biological samples. |
| Databáze: | OpenAIRE |
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