Complexes of 2-(4,6-dimethylpyrimidin-2-yl)-5-methyl-2н-pyrazol-3-ol with phenols: Formation, structure, stability
Autor: | V. V. Gurzhii, I. V. Klaptyuk, T. V. Firsanova, V. I. Krutikov, A. V. Erkin |
---|---|
Rok vydání: | 2017 |
Předmět: |
Hydrogen bond
Thermal decomposition Intermolecular force 02 engineering and technology General Chemistry 021001 nanoscience & nanotechnology 010403 inorganic & nuclear chemistry Photochemistry 01 natural sciences Endothermic process 0104 chemical sciences chemistry.chemical_compound chemistry Polymer chemistry Phenols 0210 nano-technology |
Zdroj: | Russian Journal of General Chemistry. 87:402-406 |
ISSN: | 1608-3350 1070-3632 |
DOI: | 10.1134/s1070363217030070 |
Popis: | Fusion 2-(4,6-dimethylpyrimidin-2-yl)-5-methyl-2Н-pyrazol-3-ol with phenols leads to the formation of complexes which exist due to a system of intermolecular N···H–O hydrogen bonds. The complexes are stable at high temperatures: their melting and subsequent thermolysis are accompanied by endothermic effects. |
Databáze: | OpenAIRE |
Externí odkaz: |