Hydroboration/Intramolecular Reduction of Allyl Ketones with (Diisopinocampheyl)borane: A Convenient Synthesis of Enantiomerically Enriched 1,4-Diols

Autor:	Kevin L. Bobbitt, Gary A. Molander
Rok vydání:	1994
Předmět:	chemistry.chemical_classification Ketone organic chemicals Organic Chemistry Diol Borane chemistry.chemical_compound Hydroboration chemistry Cascade reaction Intramolecular force Organic chemistry Stereoselectivity Aliphatic compound
Zdroj:	The Journal of Organic Chemistry. 59:2676-2678
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo00089a005
Popis:	The hydroboration of a variety of allyl ketones with (-)-(diisopinocam- pheyl)borane precedes a highly stereoselective intramolecular reduction of the ketone, providing a convenient procedure for the preparation of enantiomerically enriched alcohols
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9cce12c3b1250dcdb76e080cb7f5ec7a https://doi.org/10.1021/jo00089a005 Zobrazit plný text záznamu