In situsynthesis of pyridinium-based ionic porous organic polymers with hydroxide anions and pyridinyl radicals for halogen-free catalytic fixation of atmospheric CO2

Autor:	Chen Guojian, Minman Tong, Zixuan Xu, Zhouyang Long, Yadong Zhang, Ke Liu, He Huang, Yan Liu, Zhiheng Qiu
Rok vydání:	2022
Předmět:	chemistry.chemical_classification Radical Ionic bonding Polymer Pollution Catalysis chemistry.chemical_compound chemistry Ionic liquid Polymer chemistry Environmental Chemistry Hydroxide Knoevenagel condensation Pyridinium
Zdroj:	Green Chemistry. 24:136-141
ISSN:	1463-9270 1463-9262
DOI:	10.1039/d1gc03465k
Popis:	Pyridinium-based ionic porous organic polymers (Py-iPOPs) were constructed from newly-designed acetonitrile-functionalized ionic liquids and multi-carbaldehyde monomers by the base-catalyzed Knoevenagel condensation. The obtained Py-iPOPs having in situ formed hydroxide anions and pyridinyl radicals were regarded as efficient metal-free and halogen-free heterogeneous catalysts for atmospheric CO2 fixation under mild conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9cc9b5e8a99c7391d2df521c7ed62d53 https://doi.org/10.1039/d1gc03465k Zobrazit plný text záznamu