Synthesis and Thermal Curing of Aryl-Ethynyl-Terminated coPOSS Imide Oligomers: New Inorganic/Organic Hybrid Resins

Autor:	Ren-Zhi Jin‡, Derek A. Schorzman, Michael E. Wright, Frank J. Feher,‡ and
Rok vydání:	2002
Předmět:	Phthalic anhydride Condensation polymer Materials science General Chemical Engineering Aryl Thermosetting polymer General Chemistry Oligomer chemistry.chemical_compound Monomer chemistry Polymer chemistry Materials Chemistry Thermal stability Imide
Zdroj:	Chemistry of Materials. 15:264-268
ISSN:	1520-5002 0897-4756
DOI:	10.1021/cm020238h
Popis:	A new bis(amino)-functionalized POSS monomer was prepared and characterized with the formula diexo-(c-C5H9)8Si8O11(p-C6H4NH2)2 . The new POSS monomer (1−10 mol %) along with diamines 1,3-bis(3-aminophenoxy)benzene (APB) and 3,4‘-oxydianiline (ODA) and were copolymerized with 4,4‘-oxydiphthalic anhydride (ODPA) and two reactive end-caps, 4-(arylethynyl)phthalic anhydride {where aryl = phenyl and 9-anthracenyl} to afford a series of new inorganic/organic imide oligomers. The oligomers containing 1% and 10% POSS gave similar Tg data (≈191 and 203 °C) as the pure organic imide oligomers and were shown to thermally cure to afford solvent-resistant and high Tg resins. The thermal curing kinetic data for the 10%-POSS-containing imide was obtained. The kinetic data showed the rate of thermal curing to be unaffected (within experimental deviation) by the addition of the POSS units.
Databáze:	OpenAIRE
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