Significance of the physical modification of polycaproamide by antioxidants for its stabilization during thermo-oxidative ageing

Autor:	V.A. Kargin, T.I. Sogolova, T.K. Shaposhnikova, N.I. Korshunova
Rok vydání:	1974
Předmět:	chemistry.chemical_classification Physical structure Chemical engineering Chemistry Ageing General Engineering Plasticizer Organic chemistry Polymer Oxidative phosphorylation
Zdroj:	Polymer Science U.S.S.R.. 16:90-96
ISSN:	0032-3950
DOI:	10.1016/0032-3950(74)90120-8
Popis:	It is shown that antioxidants influence the supermolecular structure of polycaproamide (PCA) in different ways: they may be structurally inert, or plasticizers, or artificial nuclei for structure formation. Transformation of the supermolecular structure during the synthesis of PCA or under conditions of reprocessing involving the introduction of nucleating or plasticizing antioxidants compresses the physical structure of the polymer, thus adding considerably to the stabilizing effect of the antioxidants. The significance and correlation of physical modification with respect to the volume and surface of the polymer during PCA stabilization under conditions of thermooxidative ageing is brought to light.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9c68b1c3c9e83f760219db7e28dad9cd https://doi.org/10.1016/0032-3950(74)90120-8 Zobrazit plný text záznamu