Electrospun SnO2 and its composite V2O5 nanofibers for thermoelectric power generator
| Autor: | Mohana Priya Subramaniam, Arjun Satheesh, Byung Jin Cho, A. A. Alagiriswamy, Geetha Arunachalam, Ramamurthi Kandaswamy, Pandiyarasan Veluswamy |
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| Rok vydání: | 2021 |
| Předmět: |
Nanocomposite
Materials science Composite number Nanotechnology 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Electrospinning 0104 chemical sciences Electronic Optical and Magnetic Materials Biomaterials Thermoelectric generator Nanofiber Seebeck coefficient Thermoelectric effect Materials Chemistry Ceramics and Composites Fiber 0210 nano-technology |
| Zdroj: | Journal of Sol-Gel Science and Technology. 98:183-192 |
| ISSN: | 1573-4846 0928-0707 |
| DOI: | 10.1007/s10971-020-05443-4 |
| Popis: | Nanofibers have attracted attention in the field of thermoelectric (TE) because of their remarkable properties; abundance, lightweight with the high-surface area-to-volume ratio, low thermal conductivity, mechanically stable, and non-toxic. In applications, like TE wearable device for energy harvesting, development of new composite nanofibers holds more significant potential with the targeted specifications. In our research, we have investigated for the first-time fiber nanocomposites for the application of wearable power generator in terms of TE energy. The electrospun technique attracts in the development of nanostructured materials in the field of thermoelectric power generation. The significance of this paper is to flourish the wearable device materials of 1D vanadium oxide/tin oxide (V2O5/SnO2) composite nanofibers synthesized using sol–gel method followed by electrospinning process. The structural and morphology properties of SnO2 fibers belong to tetragonal structure and nanocomposite relates to tetragonal (SnO2) and orthorhombic (V2O5) structure, diameter in the range of 100–400 nm. The high-surface area to volume ratio of nanofiber allowed more significant phonon scattering and enhance the efficiency. The nanofiber exhibits the outstanding TE properties of the Seebeck coefficient and power factor of 20–100 V/K and 0.3–1.6 µW/K2m at room temperature to 400 K, which is the highest among the fiber SnO2 and its composites. The nanofibers integration on wearable devices paves the way towards ultralight, thermally stable, tunable density and mechanically flexibile are unique, where nanocomposite offers a new opportunity to thermoelectric applications. |
| Databáze: | OpenAIRE |
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