The reaction between oxalatotetraammine-cobalt(III) ion and hydroxide ion in aqueous solution

Autor:	Malcolm C. Powell, Michael B. Davies, L.S. Bark
Rok vydání:	1978
Předmět:	Aqueous solution Polymers and Plastics Inorganic chemistry chemistry.chemical_element Rate equation Ring (chemistry) Oxalate Ion chemistry.chemical_compound chemistry Sodium hydroxide Materials Chemistry Hydroxide Cobalt
Zdroj:	Journal of Inorganic and Nuclear Chemistry. 40:1661-1664
ISSN:	0022-1902
DOI:	10.1016/0022-1902(78)80345-5
Popis:	The rate of the reaction between sodium hydroxide and oxalatotetraamminecobalt(III) ion was measured for a variety of hydroxide ion concentrations and at four temperatures. The rate law below 333 K is given by k obs = k 0 + k 2 [OH − ] 2 and above 333 K is shown to be k obs = k 0 + k 1 [OH − ]. The reaction proceeds with a single rate controlling step, which is interpreted as oxalate ring opening. This is followed by a rapid oxalate loss step.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9c6129dcf171a14c27426e99c15d5493 https://doi.org/10.1016/0022-1902(78)80345-5 Zobrazit plný text záznamu