High-spin Schiff-base dinuclear iron(III) complexes bridged by N-oxide ligands

Autor:	Radovan Herchel, L'ubor Dlháň, Milan Gembický, Ivan Nemec, Franz Renz, Roman Boča
Rok vydání:	2009
Předmět:	Schiff base Denticity Chemistry Magnetism Ligand Bridging ligand Photochemistry Magnetic susceptibility Inorganic Chemistry Magnetization Bipyridine chemistry.chemical_compound Crystallography Materials Chemistry Physical and Theoretical Chemistry
Zdroj:	Inorganica Chimica Acta. 362:4754-4759
ISSN:	0020-1693
Popis:	Synthesis and structure of dinuclear complexes [{FeIII(L5)}b{FeIII(L5)}](BPh4)2, where L5 is a pentadentate Schiff-base ligand, b is a bidentate N-oxide bridging ligand based on bipyridine, is reported. Magnetic behavior is investigated in terms of the magnetic susceptibility, magnetization, and Mossbauer spectroscopy revealing that the complexes are high-spin over the whole temperature region.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9c51e4d33ea366ce8454c08a22c27c78 https://doi.org/10.1016/j.ica.2009.06.057 Zobrazit plný text záznamu Full Text from ScienceDirect