A neutral vicinal silylene/phosphane supported six-membered C2PSiAu2 ring and a silver(i) complex

Autor:	Mohd Nazish, Han Bai, Christina M. Legendre, Regine Herbst-Irmer, Lili Zhao, Dietmar Stalke, Herbert W. Roesky
Rok vydání:	2022
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 58:12704-12707
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d2cc04163d
Popis:	We report on the hybrid bidentate silylene and phosphane ligand (1) stabilized Au which are capable of forming a gold containing six-membered ring (2). 2 exhibits an intramolecular aurophilic interaction, which is supported by DFT calculations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9c2925f05b92075cacc4974cd45ef7f8 https://doi.org/10.1039/d2cc04163d Zobrazit plný text záznamu