Photopromoted carbonylation of olefins with carbon dioxide and labelling studies with13CO2 and13CH3OH

Autor: Xiangsheng Wang, Jingmei Yin, Jiehan Hu, Yingping Jia, Guangyun Zhou, Dabin Gao
Rok vydání: 2003
Předmět:
Zdroj: Chinese Science Bulletin. 48:2180-2182
ISSN: 1861-9541
1001-6538
DOI: 10.1007/bf03182847
Popis: Photopromoted carbonylation of olefins with carbon dioxide can be completed in ambient conditions (room temperatures and atmospheric pressure) by Co(OAc)2 catalysis. It was found that in carbonyl carbons of methyl ester of aliphatic acid 50% is from CO2 and the other 50% from CH3OH by labelling experimental with13CO2 and13CH3OH.
Databáze: OpenAIRE
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